Kasatkina and Keys have faced each other a total of eight times in the past with the American coming out on top in seven matches.
Gauff and Andreescu have never faced one another before in competitive tennis, with the former has tasting more success this season.
Jessica Pegula and Coco Vandeweghe are scheduled to face each other in the second round of the 2022 WTA San Diego Open on October 13.
Danielle Collins and Martina Trevisan are scheduled to face each other in the second round of the 2022 WTA San Diego Open on October 13.
Andy Murray and Pedro Cachin will face each other in the round of 16 of the 2022 ATP Gijon Open October 13.
Francisco Cerundolo and Manuel Guinard will face each other in the round of 16 of the 2022 ATP Firenze Open October 13.
Lorenzo Musetti and Bernabe Zapata Miralles will face each other in the round of 16 of the 2022 ATP Firenze Open October 13.
Mackenzie McDonald and Francesco Passaro will face each other in the round of 16 of the 2022 ATP Firenze Open October 13.
Alexander Bublik and Corentin Moutet will face each other in the round of 16 of the 2022 ATP Firenze Open October 13.
Felix Auger-Aliassime and Oscar Otte are scheduled to face each other in the second round of the 2022 ATP Firenze Open on October 13.