The surprise Serie A leaders have won all their matches in this group and have a chance to make it six out of six on Tuesday.
A run of four successive victories in Serie A has sent AC Milan up to third in the table. They have 26 points from 11 games and are six points shy of leaders Napoli.
Sitting at the top of the Serie A table, Napoli have 29 points from 11 games. They have won nine, drawn two and are yet to lose a single match.
Roma will host Napoli in a Serie A fixture at the stadio Olimpico on Sunday night.
Napoli will host Bologna in a Serie A fixture at Stadio Diego Armando Maradona on Sunday evening.
Napoli will host Ajax in a UEFA Champions League fixture at the Diego Armando Maradona stadium on Wednesday.
Ajax will host Napoli in a UEFA Champions League fixture at the Amsterdam Arena on Tuesday night.
Serie A leaders Napoli will travel to San Siro to take on defending champions AC Milan on Sunday night.
Napoli and Rangers will be coming up against each other in the matchday two of UEFA Champions League group stage 2022/23.
The Wednesday night clash at the Stadio Diego Armando Maradona will see two sides with contrasting forms taking on each other.