In a Serie A top of the table clash, Napoli will host Juventus at the Diego Armando Maradona stadium on Friday night.
Serie A heavyweights Inter Milan and Napoli will go head to head in their first competitive game following the World Cup break on Wednesday night.
Despite being the best team in Italy this season, Napoli failed to win against Villareal in their previous friendly match.
Napoli will take on Crystal Palace in a friendly match at Regnum Carya Golf and Spa Resort in Turkey on Sunday.
In a Serie A top of the table clash, Atalanta will host leaders Napoli at Gewiss Stadium on Saturday.
Napoli are topping both Serie A and their Champions League groups. They have 32 points from 12 games in the league.
The surprise Serie A leaders have won all their matches in this group and have a chance to make it six out of six on Tuesday.
A run of four successive victories in Serie A has sent AC Milan up to third in the table. They have 26 points from 11 games and are six points shy of leaders Napoli.
Sitting at the top of the Serie A table, Napoli have 29 points from 11 games. They have won nine, drawn two and are yet to lose a single match.
Roma will host Napoli in a Serie A fixture at the stadio Olimpico on Sunday night.