Brazil came from behind to beat Colombia 2-1 at Olympic stadium on Wednesday to seal three points in the Group A fixture of Copa America 2021.
Los Blancos produced a late fightback to beat Villarreal, but it was not enough as Atletico Madrid won their match to win the La Liga title.
Following yesterday's draw between Barcelona and Atletico, Real Madrid have a chance to jump to the top of the table.
Chelsea overcome Real Madrid’s challenge to win 2-0 at Stamford Bridge in the second leg of the Champions League.
Atletico Madrid maintain their slender lead at the top of the La Liga points table after a 0-1 victory against Elche on Saturday.