Deepika Kumari was knocked out in straight sets by An San as India's archery hopes now rest on Atanu Das.
Lovlina Borgohain became the second medal winner from India after entering the 2020 Tokyo Olympics semifinal.
Manu Bhaker and Rahi Sarnobet failed to qualify for the medal event in the 25m air pistol event as the Tokyo Olympics 2020 campaign was over for the youngster.
In the one arrow shoot-off, the Russian scored a 7. She knew she was well off the mark, and World Number 1 grabbed that opportunity and scored a perfect 10.
India will be praying that Deepika Kumari, Manu Bhaker and PV Sindhu all continue to make the country proud in Tokyo Olympics 2020.
He had an opportunity to finish in the first place but was only marginally beaten to it by Abeiku Jackson of Ghana.
India put up a brilliant show on the sixth day of the Tokyo Olympics 2020 as they looked to increase their medal tally.
Atanu Das was in fine form as he defeated South Korea's Oh Jin Hyuk in a thrilling archery shoot-off to enter the quarterfinal.
Fencer Bhavani Devi has already created history by becoming the first Indian to qualify for the sport at such a big stage.
July 29 can prove to be an important day for India at the Olympics as a number of top athletes will be in action.