Kaladzinskaya's loss meant bad news for Phogat as she would have had a chance in repechage had the Belarusian reached the final.
Vinesh Phogat lost in the quarterfinal, knocking her out of contention for gold.
The India men's hockey team created history in Tokyo Olympics 2020 when they won the bronze by beating Germany.
Ravi Kumar Dahiya beat Nurislam Sanayev of Kazakhstan in the men’s freestyle 57 kg semifinal. He will face Uguev Zavur in the final.
Sky Brown broke Margery Hinton's 93-year-old record to become the youngest athlete to represent Team Great Britain.
The Brazil men's football team entered the final for the second successive time as they beat Mexico on penalties.
The men's hockey side fell to Belgium 5-2 in the semi-final after a valiant fight, and will face Germany for the bronze medal.
Toor could only manage a best throw of 19.99m and it was not good enough for him to make it through to the final.
Earlier at the Olympics, Biles had withdrawn from all of her individual events as she cited mental health reasons.
The United States women's football team failed to clinch the opportunity to challenge for gold after their heartbreaking 1-0 loss to Canada.