Ashwin is just four wickets short of former Indian cricketer Harbhajan Singh, the second best Indian spinner in Tests behind Anil Kumble.
The Indian skipper has only managed to score a total of 124 runs, with an average of 24.80, in five innings spanning over three Test matches.
The 39-year-old cricketer is one of only two England bowlers that have taken more than 300 wickets at home in Test matches.
India did make a good comeback after being bundled out for just 78 in the first innings, but it was never going to be enough.
Cheteshwar Pujara played a superb knock of 91 but he could not prevent India losing the Leeds Test against England.
Cheteshwar Pujara had a point to prove in the third Test, and he rose brilliantly to the challenge scoring a brilliant 91.
Pujara carried the team until the end of the day and played with exceptional patience and composure against the aggressive pace attack.
The duo remained unbeaten throughout the session and while India still trail over 200 runs, there would be some sort of confidence in the dressing room.
Virat Kohli has struggled in the last couple of years, having not hit a century since November 2019.
The England skipper was the star of the day as he scored his third century in as many Test matches with a fantastic 121.