| No. of times Played | 10 |
|
|
|
| Win % | 70% |
| H2H |
| Last Played | 2021 | First Played | 2017 |
| Tournament | US Open | Tournament | ATP Masters 1000 Rome |
| Round | Semi-Finals | Round | Finals |
| Winner | Novak Djokovic | Winner | Alexander Zverev |
| Score | 64 26 46 64 26 | Score | 64 63 |
| No. of times Played | 9 |
|
|
|
| Win % | 44% |
| H2H |
| Last Played | 2021 | First Played | 2016 |
| Tournament | ATP Cup | Tournament | St. Petersburg |
| Round | Semi-Finals | Round | Round of 16 |
| Winner | Daniil Medvedev | Winner | Alexander Zverev |
| Score | 63 36 57 | Score | 63 75 |
| No. of times Played | 9 |
|
|
|
| Win % | 67% |
| H2H |
| Last Played | 2021 | First Played | 2018 |
| Tournament | ATP Masters 1000 Cincinnati | Tournament | ATP Masters 1000 Canada |
| Round | Semi-Finals | Round | Quarter-Finals |
| Winner | Alexander Zverev | Winner | Stefanos Tsitsipas |
| Score | 64 36 76 | Score | 63 67 |
| No. of times Played | 9 |
|
|
|
| Win % | 67% |
| H2H |
| Last Played | 2021 | First Played | 2016 |
| Tournament | ATP Masters 1000 Rome | Tournament | ATP Masters 1000 Indian Wells |
| Round | Quarter-Finals | Round | Round of 16 |
| Winner | Rafael Nadal | Winner | Rafael Nadal |
| Score | 36 46 | Score | 76 |
| No. of times Played | 4 |
|
|
|
| Win % | 25% |
| H2H |
| Last Played | 2021 | First Played | 2018 |
| Tournament | ATP Masters 1000 Madrid | Tournament | ATP Masters 1000 Rome |
| Round | Finals | Round | Round of 32 |
| Winner | Alexander Zverev | Winner | Alexander Zverev |
| Score | 67 | Score | 75 62 |
| No. of times Played | 5 |
|
|
|
| Win % | 40% |
| H2H |
| Last Played | 2020 | First Played | 2014 |
| Tournament | Nitto ATP Finals | Tournament | Kitzbuhel |
| Round | Round Robin | Round | Round of 32 |
| Winner | Alexander Zverev | Winner | Diego Schwartzman |
| Score | 63 46 63 | Score | 16 06 |
| No. of times Played | 7 |
|
|
|
| Win % | 43% |
| H2H |
| Last Played | 2019 | First Played | 2016 |
| Tournament | ATP Masters 1000 Shanghai | Tournament | Halle |
| Round | Quarter-Finals | Round | Semi-Finals |
| Winner | Alexander Zverev | Winner | Alexander Zverev |
| Score | 63 67 | Score | 76 |
| No. of times Played | 11 |
|
|
|
| Win % | 73% |
| H2H |
| Last Played | 2021 | First Played | 2016 |
| Tournament | ATP Masters 1000 Madrid | Tournament | Beijing |
| Round | Semi-Finals | Round | Round of 32 |
| Winner | Alexander Zverev | Winner | Alexander Zverev |
| Score | 63 64 | Score | 46 61 63 |
