These two countries played earlier in the Nations League when Portugal won 4-0 in their home, while Switzerland prevailed 1-0 in the reverse leg.
Defying the odds, Morocco started the tournament with a draw over Croatia before defeating Belgium and Canada to top the group with seven points.
The South American nation came to Qatar as the favourites to lift the trophy and have held that tag despite suffering a mini blip in their final group game.
The Monday night encounter will see the South American nation as the overwhelming favourite, thanks to their impeccable history in the competition.
The Tottenham Hotspur forward is yet to open his scoring in Qatar, as Gareth Southgate’s side prepares for their first knockout round contest.
The Three Lions had a positive group stage campaign, which saw them top Group B with seven points from three games.
Louis van Gaal’s side were placed in Group A and were always expected to be the favourites to top the group and they did not disappoint their supporters.
After losing their opener 4-1 to France, Australia defeated Tunisia and Denmark to finish second in Group D.
The superior experience and quality will be heavily in favour of the South American nation, making them the clear favourites in this fixture.
Placed in Group A, the Netherlands comfortably secured the first spot with seven points from three games.