In the semi-finals, the men in blue led by captain Filippo Volandri will face the winner of Germany's international match against Canada.
Eight teams remain and will compete in the quarterfinals beginning on Tuesday. In the first quarterfinal, Australia will face the Netherlands.
Currently, the Great Britain team consists of Cameron Norrie, Daniel Evans, Andy Murray and Joe Salisbury.
The likes of Novak Djokovic, Andy Murray, Marin Cilic, Alexander Zverev, Carlos Alcaraz and several others will be a part of the historic ITF tournament.
Daniil Medvedev has won over 60 matches in 2021, making him the first player to achieve this feat.
In the first match, Lorenzo Sonego delivered on his Davis Cup Finals debut to give Italy a 1-0 lead over the United States, defeating Reilly Opelka.
The 34-year-old did not face a break point and won nine of the last 11 games to secure the victory in 60 minutes.