Real Madrid began their campaign with a 4-2 thrashing of Deportivo Alaves on Saturday courtesy of a brace from Karim Benzema and goals from Nacho and Vinicius.
The 61-year-old Spaniard, who spent six years at Everton's Merseyside rivals Liverpool, replaces Carlo Ancelotti on a three-year deal.
The ceremonial signing of the contract will take place tomorrow with Florentino Pérez, after which Ancelotti will address the media.
Everton beat West Ham 1-0 at the London stadium on Sunday courtesy of a first half goal from Dominic Calvert-Lewin.
Everton manager Carlo Ancelotti is confident his side will put up a good showing against West Ham United in their Premier League match on Sunday.
Everton and West Ham United will face off in a Premier League match that could dictate their chances of playing continental football next season.
Everton were beaten 1-2 at Goodison park on Saturday night courtesy of goals from Ollie Watkins and Anwar El-Ghazi.
Manchester City will travel to Selhurst Park on Saturday to take on Crystal Palace in their Premier League fixture.
Everton beat Arsenal 1-0 at the Emirates courtesy on a Bernd Leno own goal to boost their Champions League qualification dream.
Jose Mourinho and Pep Guardiola have cracked the code to rule the European world.